普鲁士蓝色类型的高质子导电性和磁性排序的干扰效应
Shin-Ichi Ohkoshi1, Kosuke Nakagawa, Keisuke Tomono
1Department of Chemistry, School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan. ohkoshi@chem.s.u-tokyo.ac.jp
Journal of the American Chemical Society
|April 28, 2010
概括
和协调聚合物具有高质子导电性. 研究人员发现,在磁相过渡温度附近,磁性排序和离子运输之间存在相互作用.
科学领域:
- 材料科学 材料科学 材料科学
- 固态化学 固态化学
- 磁力学 磁力学 是一种
背景情况:
- 在协调聚合物中的质子导电性对于能源应用至关重要.
- 了解磁性和离子运输之间的关系是一个持续的挑战.
研究的目的:
- 合成和描述基于和的新型协调聚合物.
- 研究这些材料的质子导电性和磁性.
- 探索磁性排序和离子导电之间的合.
主要方法:
- 合成 (II) 六甲 (III) 和 (II) 六甲 (III) 协调聚合物.
- 使用电化学阻抗光谱学进行质子导电性测量.
- 测量磁性易感度以确定磁性排序和相位过渡.
主要成果:
- 实现了高质子导电率为1.2 x 10 (((-3) S cm ((-1) 的Co[Cr ((CN)) 6)) 2/3).zH ((2) O和1.6 x 10 ((-3) S cm ((-1) 的V[Cr ((CN)) 6)) 2/3).zH ((2) O.
- 在磁相过渡温度以下观察到磁性排序和离子导电之间的干扰效应.
- 结果表明,磁性排序对质子运输有很大的影响.
结论:
- 和协调聚合物显示出对潜在应用具有有前途的质子导电性.
- 观察到的磁性和离子性质之间的合为设计功能性材料提供了新的途径.
- 对磁离子合机制的进一步研究可能会导致电化学设备的先进材料.
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