室温合成导致纳米晶体的Ag(2)V(4)O(11)
Frédéric Sauvage1, Vincent Bodenez, Jean-Marie Tarascon
1Department of Chemistry, Northwestern University, Evanston, Illinois 60208-3113, USA.
研究人员开发了一种新的白银氧化化合物用于电池. 这种材料可以同时进行白银和的氧化还原反应,大大提高了阴极容量,改善了能量存储.
科学领域:
- 材料科学 材料科学 材料科学
- 无机化学 无机化学
- 电化学 电化学 电化学
背景情况:
- 在储能应用方面,正在探索银瓦纳达.
- 三级系统为具有独特性质的新型化合物提供途径.
研究的目的:
- 在室温下研究Ag2O/V2O5/HF三元系统.
- 为了合成和表征新的白银氧化化合物和纳米晶体Ag{2) V{4) O{11) (SVO).
- 为了评估SVO作为正极材料的电化学性能.
主要方法:
- 系统的室温组合研究Ag{2}O/V{2}O{5}/HF{aq}).
- 沉合成银瓦纳酸盐和银瓦纳氧化物.
- 纳米晶体Ag(2)V(4)O(11) (SVO) 形态和尺寸的表征.
- 用于离子电池应用的SVO的电化学测试.
主要成果:
- 沉各种银酸盐和新型的Ag(4) V ((2) O ((6) F ((2) 和Ag(3) VO ((2) F ((4) 化合物.
- 成功合成了具有针状形态 (10-15 x 50-200 nm) 的纳米晶体Ag(2) V(4) O(11) (SVO).
- 在SVO中证明可逆的Ag(+) /Li(+) 位移反应.
- 在C速度下达到320 mAh/g的增强阴极重力测量容量,在5C时达到>250 mAh/g.
结论:
- 在Ag(2) O/V(2) O(5) /HF(aq)) 系统中,可以产生多种银酸盐和氧化物.
- 纳米晶体SVO表现出独特的反应性,并使同时进行Ag和V氧化还原过程.
- 作为先进电池的高容量阴极材料,SVO显示出显著的潜力.
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