在量子点敏感太阳能电池中注入和再组合的设计
Eva M Barea1, Menny Shalom, Sixto Giménez
1Photovoltaic and Optoelectronic Devices Group, Departament de Fisica, Universitat Jaume I, 12071 Castello, Spain.
Journal of the American Chemical Society
|April 29, 2010
概括
分子二极管和符合性涂层显著增强量子点太阳能电池 (QDSCs). 表面处理提高了光伏性能600%,提高了能源转换效率.
科学领域:
- 材料科学 材料科学 材料科学
- 纳米技术纳米技术
- 可再生能源可再生能源是可再生能源.
背景情况:
- 半导体量子点 (QD) 为光伏应用提供可调节的光电子特性.
- 量子点敏感太阳能电池 (QDSC) 是可再生能源发展的一个有希望的领域.
- 控制充电注入和重组是提高QDSC效率的关键.
研究的目的:
- 调查分子二极体和符合性涂层对QDSC性能的影响.
- 优化表面修改策略,以增强充电注入和减少重组.
- 为了将表面处理与光伏设备性能相关联.
主要方法:
- 使用半孔TiO(2) 电极和通过化学浴沉积 (CBD) "在现场"培养的CdSe QDs制造QDSC.
- 用符合ZnS的涂层对CdSe表面进行修改,并对分子二极管 (DT) 进行接种.
- 系统测试不同的表面处理序列 (DT+ZnS) 和使用表面光伏和化学电容量测量进行表征.
主要成果:
- 优化的表面处理 (DT+ZnS) 与未经修改的电极相比,使光伏性能提高了600%.
- 取得的V (oc) = 0.488V,j (sc) = 9.74mA/cm2),FF = 0.34,整体效率为1.60%.
- 光伏性能与CdSe和TiO的相对波段位置以及重组电阻相关.
结论:
- 使用分子二极管和ZnS符合性涂层的表面修饰是提高QDSC性能的有效策略.
- 优化的表面处理显著改善了充电注入,减少了重组损失.
- 这种方法为提高基于QD的太阳能电池的能量转换效率提供了一条途径.
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