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Updated: Jun 12, 2026

Isolating Free Carbenes, their Mixed Dimers and Organic Radicals
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Isolating Free Carbenes, their Mixed Dimers and Organic Radicals

Published on: April 19, 2019

1,3-二极体的二极根性质与它们对乙烯或乙的反应性之间存在明显的相关性

Benoit Braida1, Christof Walter, Bernd Engels

  • 1CNRS UMR 7616, Laboratoire de Chimie Théorique, UPMC Université Paris 06, Case Courrier 137, 4 Place Jussieu, 75252 Paris, France. braida@lct.jussieu.fr

Journal of the American Chemical Society
|May 21, 2010
PubMed
概括

1,3-二极体的二极根性质对于1,3-二极体循环加法反应至关重要. 一种拟议的机制涉及二极极扭曲到反应性二极极态,使无障碍的循环添加成为可能.

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