硫酸盐离子在远距离的水中形成了水的图案
Jeremy T O'Brien1, James S Prell, Matthew F Bush
1Department of Chemistry, University of California, Berkeley, California 94720-1460, USA.
Journal of the American Chemical Society
|June 4, 2010
概括
硫酸盐离子 (SO(4)(2-)) 影响水的结构远远超出了它的周围. 这种通过红外光解离谱学观察到的远程效应是理解霍夫迈斯特系列的关键.
科学领域:
- 物理化学 物理化学
- 化学物理 化学物理
- 频谱学是一种光谱学方法.
背景情况:
- 霍夫迈斯特系列描述了基于它们对蛋白质溶解度的影响的离子的排序.
- 驱动霍夫迈斯特效应的精确分子机制仍然不完全理解.
- 研究离子-水相互作用对于阐明这些效应至关重要.
研究的目的:
- 为了调查霍夫迈斯特系列的化学起源.
- 了解硫酸盐离子对水结构的远程影响.
主要方法:
- 使用红外光解离 (IRPD) 光谱法进行检测.
- 硫酸盐离子-水集群的IRPD光谱 (SO(4) ((2-) ((H(2) O) ((n)) 被分析为不同的水合数 (n).
主要成果:
- 对于拥有超过43个水分子 (n > 43) 的星团,出现了 ~3710 cm(-1 的独特光谱带.
- 这个带表示在外水分子中存在"自由"OH组,类似于散装水.
- 在较小的集群中 (n <= 43) 缺少这一带,表明结构性过渡.
结论:
- 硫酸二对水结构产生长远的影响.
- 这种扩展的结构干扰是导致硫酸盐观察到的霍夫迈斯特行为的一个重要因素.
相关概念视频
Ionic Association
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Aqueous Solutions and Heats of Hydration
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Ions as Acids and Bases
Salts with Acidic Ions
Salts are ionic compounds composed of cations and anions, either of which may be capable of undergoing an acid or base ionization reaction with water. Aqueous salt solutions, therefore, may be acidic, basic, or neutral, depending on the relative acid-base strengths of the salt’s constituent ions. For example, dissolving the ammonium chloride in water results in its dissociation, as described by the equation:
Salts are ionic compounds composed of cations and anions, either of which may be capable of undergoing an acid or base ionization reaction with water. Aqueous salt solutions, therefore, may be acidic, basic, or neutral, depending on the relative acid-base strengths of the salt’s constituent ions. For example, dissolving the ammonium chloride in water results in its dissociation, as described by the equation:
Factors Affecting Solubility
Compared with pure water, the solubility of an ionic compound is less in aqueous solutions containing a common ion (one also produced by dissolution of the ionic compound). This is an example of a phenomenon known as the common ion effect, which is a consequence of the law of mass action that may be explained using Le Chȃtelier’s principle. Consider the dissolution of silver iodide:
Solubility Equilibria: Ionic Product of Water
Pure water is a weak electrolyte; only a small amount ionizes into hydrogen and hydroxide ions. At any given temperature, the concentration of undissociated water is almost constant, so the ionic product of water is the product of the hydrogen and hydroxide ion concentrations, denoted as Kw. The square root of Kw gives the individual ion concentrations.
The ionic product of water varies with temperature, and its value is 1.0 x 10−14 at standard experimental conditions. Per Le Chatelier's...
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