大规模的火山SO2氧化和硫酸盐气溶沉积在Cenozoic北美
Huiming Bao1, Shaocai Yu, Daniel Q Tong
1Department of Geology and Geophysics, Louisiana State University, Baton Rouge, Louisiana 70803-4101, USA. bao@lsu.edu
Nature
|June 19, 2010
概括
北美中古时代的火山爆发导致了硫酸盐气溶沉积. 性云水条件有利于臭氧驱动的二氧化硫氧化,与今天的酸性云不同.
科学领域:
- 地质化学 地质化学
- 大气科学 大气科学
- 古气候学 古气候学
背景情况:
- 火山爆发将大量的二氧化硫 (SO2) 释放到大气中.
- SO2) 氧化成硫酸盐气溶会影响地球的辐射平衡,臭氧和生物生产力.
- 了解SO2氧化途径对于解释过去的火山活动和大气条件至关重要.
研究的目的:
- 用硫和三重氧同位素在中代代代的岩沉积物中研究SO(2) 氧化途径.
- 为了重建过去的大气条件和火山爆发的影响从硫酸盐气溶.
主要方法:
- 在从岩沉积物中提取的大气硫酸盐中分析硫和三重氧同位素.
- 使用一个三维大气硫化学和运输模型.
- 识别硫酸盐沉积事件及其化学特征.
主要成果:
- 在北美北部高平原中期 (3400万-700万年前) 发现了七次与喷发相关的硫酸盐气溶沉积事件.
- 两个灰显示了类似的硫酸盐混合模式与两个不同的二级硫酸盐.
- 建模表明,观察到的硫酸盐特征最初需要性云水和臭氧主导的SO2氧化.
结论:
- 北部高原的中古时代云水可能经常性,与当今弱酸性条件形成鲜明对比.
- 在这些过去的火山事件中,臭氧主导的SO2氧化途径是普遍存在的.
- 大陆沉积物中的大气二次硫酸盐为过去的火山活动和大气化学提供了宝贵的地质档案.
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