抗铁磁/铁磁核/外MnO纳米颗粒中的尺寸依赖的被动化外和磁性特性
Alberto López-Ortega1, Dina Tobia, Elin Winkler
1Centre d'Investigació en Nanociència i Nanotecnologia (ICN-CSIC), Campus Universitat Autònoma de Barcelona, E-08193 Bellaterra, Spain.
Journal of the American Chemical Society
|June 24, 2010
概括
在氧化 (MnO) 核心纳米粒子上的被动化的阶段取决于尺寸,影响磁性特性. 较小的纳米颗粒显示了增强的磁性异构性和尼尔温度.
科学领域:
- 材料科学 材料科学 材料科学
- 纳米技术纳米技术
- 固态物理 固态物理
背景情况:
- 核心/外纳米粒子通过结合不同的材料提供可调节的特性.
- 氧化物 (MnO) 呈现出不同的磁性行为,取决于相位和结构.
研究的目的:
- 为了研究双磁核/外纳米粒子的磁性特性.
- 了解纳米粒子大小对外阶段和磁性特征的影响.
主要方法:
- 核心/外纳米粒子与MnO核心和铁磁外的合成.
- 结构特征以确定外阶段 (gamma-Mn(2) O(3) 或Mn(3) O(4).
- 磁性特征测定以评估尼尔温度,磁性异构性和磁域行为.
主要成果:
- 相组合因纳米粒子大小而异:玛-Mn(2) O(3) 在较小的粒子中占主导地位,Mn(3) O(4) 在较大的粒子中增加.
- 在MnO核心中,Nel温度 (T(N)) 和磁性异质性显著增加,核心尺寸下降.
- 在高温下观察到MnO的持久磁矩和不寻常的磁域温度依赖.
结论:
- 纳米粒子大小是控制MnO核心/外系统相位和磁性特性的关键因素.
- 取决于尺寸的磁现象,包括增强的T (N) 和异形性,对于基本的理解和潜在的应用具有重要意义.
- 这项研究突出了纳米材料中尺寸,相位和磁性之间的复杂相互作用.
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