原子碳纳米线在石墨烯电极之间的电子传输特性
Lei Shen1, Minggang Zeng, Shuo-Wang Yang
1Department of Physics, 2 Science Drive 3, National University of Singapore, Singapore 117542, Singapore.
Journal of the American Chemical Society
|August 4, 2010
概括
线性原子碳电线为电子设备提供了潜力. 运输特性取决于线长和杂质,氧气可能会限制导电性,双链表现出独特的电阻效应.
科学领域:
- 凝聚物质物理学 凝聚物质物理学
- 材料科学 材料科学 材料科学
- 纳米技术纳米技术
背景情况:
- 从石墨烯衍生出的线性原子碳线是新的1D结构.
- 这些电线具有潜在的应用,作为场效应晶体管中的传输通道.
- 它们独特的结构表明与纳米管或纳米带相比,它们具有独特的电子特性.
研究的目的:
- 为了研究由线性原子碳线和石墨烯形成的连接点的电子传输特性.
- 了解线长,结构缺陷和杂质对导电性的影响.
- 探索这些碳线在电子设备中的潜在应用和局限性.
主要方法:
- 结合不平衡格林函数 (NEGF) 与密度函数理论 (DFT).
- 通过各种线性原子碳线-石墨烯连接配置模拟电子运输.
- 分析结构变化和吸附杂质 (H,O) 对运输的影响.
主要成果:
- 在短线中观察到的弹道运输具有奇数的碳原子,但不是偶数的碳原子.
- 对于长于2.1纳米的电线,导电性对扭曲和H杂质有很强的抵抗力.
- 氧杂质 (环氧组) 在低偏差下显著降低导电性.
- 双原子碳链表现出负差电阻.
结论:
- 在线性原子碳电线-石墨烯连接处的电子传输对电线长度和特定杂质敏感.
- 氧杂质,可能形成环氧基,可能解释实验观察到的低导电.
- 独特的运输特性,包括双链的负差电阻,突出了它们对新型电子功能的潜力.
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