阿里尔C-H键通过电友二化通过电友二化的氨化
Amanda Kae Musch Long1, Renyuan Pony Yu, George H Timmer
1Department of Chemistry, University of Wisconsin-Madison, 1101 University Avenue, Madison, Wisconsin 53706, USA.
Journal of the American Chemical Society
|September 3, 2010
概括
化复合物经过热解,通过电友性插入到烯C-H键中产生一种新产品. 这种反应是外热的,并得到计算和热分析的支持.
科学领域:
- 有机金属化学 有机金属化学
- 无机化学 无机化学 有机化学
- 反应机制 反应机制
背景情况:
- 终端化复合物是反应性化物种的前体.
- 了解C-H键激活在催化和合成中至关重要.
研究的目的:
- 为了研究终端亚齐多复合物的热解.
- 阐明化基组插入到化基C-H键的机制.
主要方法:
- 热解Ru(2)(D(3,5-Cl(2)) PhF)(3) N(3). 热解的方法是:
- 不同扫描热度计 (DSC) 和热重力测量分析 (TGA).
- 密度函数理论 (DFT) 的计算.
主要成果:
- 在热解过程中清洁形成Ru(2) [(D(3,5-Cl(2)) PhF) ].
- 两个阶段的外热反应,总度为-215 kJ mol ((-1).
- 实验结果与DFT计算一致.
结论:
- 这项研究展示了终端化物的电友性插入到芳香C-H键的第一个例子.
- 拟议的机制涉及将化物N原子插入到基烯C-H键中.
- 这种反应为通过金属化物介导的C-H功能化途径提供了新的见解.
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