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Updated: Jun 8, 2026

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体加速的C-H激活反应:证据表明机制的切换

Keary M Engle1, Dong-Hui Wang, Jin-Quan Yu

  • 1Department of Chemistry, The Scripps Research Institute, 10550 North Torrey Pines Road, La Jolla, California 92037, USA.

Journal of the American Chemical Society
|September 22, 2010
PubMed
概括

单N受保护的氨基酸显著加快了酸的有氧化C-H化. 这种连接器调整通过将C-H裂变机制从电友拉转移到质子抽象来提高反应速率和基质范围.

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