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相关概念视频

Coordination Number and Geometry02:57

Coordination Number and Geometry

For transition metal complexes, the coordination number determines the geometry around the central metal ion. Table 1 compares coordination numbers to molecular geometry. The most common structures of the complexes in coordination compounds are octahedral, tetrahedral, and square planar.
Lattice Centering and Coordination Number02:33

Lattice Centering and Coordination Number

The structure of a crystalline solid, whether a metal or not, is best described by considering its simplest repeating unit, which is referred to as its unit cell. The unit cell consists of lattice points that represent the locations of atoms or ions. The entire structure then consists of this unit cell repeating in three dimensions. The three different types of unit cells present in the cubic lattice are illustrated in Figure 1.
Types of Unit Cells
Imagine taking a large number of identical...
Adaptability of Cytoskeletal Filaments01:12

Adaptability of Cytoskeletal Filaments

The cytoskeleton is a complex dynamic structure performing varied functions based on cellular requirements. The adaptability of the individual filaments in the cytoskeleton determines their ability to perform various functions within the cell. It can undergo rapid reorganization during processes like cell division or remain stable for several hours as in the interphase. The adaptability of these filaments depends on stringent regulatory mechanisms. The microfilament and microtubules of the...
Clathrin Coated Vesicles01:12

Clathrin Coated Vesicles

Clathrin-coated vesicles use endocytosis to transport receptors and lysosomal hydrolases from the Golgi to the lysosome in the late secretory pathway. Clathrin-mediated endocytosis was the first described endocytic process, and Clathrin-coated vesicles remain one of the most well-studied transport vesicles. The molecular machinery that generates clathrin-coated vesicles comprises over 50 proteins that precisely coordinate vesicle formation. Cell surface receptors concentrated in indented sites...
Protein Complexes with Interchangeable Parts01:57

Protein Complexes with Interchangeable Parts

Groups of proteins may form a complex where each protein in this complex has a different role in the overall execution of the complex’s function. Often some of the proteins in the complex can be replaced by a closely related variant to give a complex that contains many of the same components yet is functionally distinct.
The SCF ubiquitin ligase is a protein complex of five individual proteins. This complex attaches ubiquitin to other target proteins to mark them for degradation. In order to...
Masonry Cavity Walls01:26

Masonry Cavity Walls

Cavity walls feature a hollow space between the outer and inner wythes, connected only by corrosion-resistant metal ties. When water seeps through the outer wythe, it descends within this cavity, intercepted by flashing and eventually exiting through weep holes. To enhance moisture resistance, the inner wythe's cavity side often receives damp-proofing, doubling as an air barrier. The cavity can also house insulation to mitigate heat transfer.
Maintaining a clean cavity during construction is...

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相关实验视频

Updated: Jun 8, 2026

A Do-it-yourself System for Scheduled Feeding of Laboratory Rodents in Their Home Cage
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A Do-it-yourself System for Scheduled Feeding of Laboratory Rodents in Their Home Cage

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一个协调子,具有可适应的腔体大小.

Sebastian Mirtschin1, Adam Slabon-Turski, Rosario Scopelliti

  • 1Institut des Sciences et Ingénierie Chimiques, École Polytechnique Fédérale de Lausanne, CH-1015 Lausanne, Switzerland.

Journal of the American Chemical Society
|September 24, 2010
PubMed
概括

一个新的六核协调子显著扩大,创造了一个大腔. 这种扩张使得两个冠分子在其结构中成功封装.

科学领域:

  • 超分子化学 超分子化学
  • 协调化学 协调化学
  • 材料科学 材料科学 材料科学

背景情况:

  • 协调是具有可调节性质的超分子结构.
  • 控制腔体大小对于分子封装应用至关重要.

研究的目的:

  • 开发一个带有动态腔的六核协调.
  • 为了研究子封装多环芳香碳化合物的能力.

主要方法:

  • 六核金属有机框架的合成.
  • 可变温度X射线衍射研究结构变化.
  • 气体吸附和脱附等温,以确定空腔体积.
  • 结晶学以确认客分子的封装.

主要成果:

  • 六核协调的腔体体积发生了显著的变化,从接近零到超过500 Å.
  • 子成功地将两个冠分子封装在其扩展的腔内.
  • 结构分析证实了封装的冠烯分子的存在和方向.

结论:

  • 开发的协调体显示出可观的动态腔扩张.
  • 这种动态行为允许对大客分子 (如冠) 进行尺寸选择性封装.

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  • 这些发现为使用可适应的超分子架构的宿主-客化学和分子识别开辟了新的途径.