基于溶液的TiO2-聚合物复合介电器用于低工作电压OTFT
Joohee Kim1, Sung Hee Lim, Youn Sang Kim
1Department of Nano Science and Technology, Graduate School of Convergence Science and Technology, Seoul National University, 599 Gwanak-ro, Gwanak-gu, 151-742, Seoul, Korea.
Journal of the American Chemical Society
|October 5, 2010
概括
这项研究表明,二氧化聚合物复合材料 (TPC) 的交联反应. 密集的TPC结构来自于聚胺-协同甲和聚4-乙烯与二氧化前体之间的反应.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物化学 聚合物化学
- 纳米技术 纳米技术
背景情况:
- 二氧化聚合物复合材料 (TPC) 是重要的介电材料.
- 开发密集和稳定的TPC结构对于先进的应用是必不可少的.
- 了解交叉链接机制是物质财产控制的关键.
研究的目的:
- 为了证明和阐明一个TiO(2) - 聚合物复合物的交叉连接反应.
- 调查特定交叉连接器在形成密集的TPC结构中的作用.
- 为了确定负责复合材料结构完整性的化学相互作用.
主要方法:
- 使用TiO(2) 前体制造TiO(2) 聚合物复合物.
- 使用聚4-乙) (PVP) 作为聚合物矩阵和交叉链接器前体.
- 采用聚胺联合形式化 (PMF) 作为交联剂.
主要成果:
- 实现了TPC介电器的成功交叉连接反应.
- 观察到TPC的密集化学结构.
- PMF交叉连接器的基团与PVP的基团和TiO(2) 前体的配体发生反应.
结论:
- 交叉链接机制涉及PMF和PVP之间的反应,导致密集的TPC.
- 在形成复合物的结构中,PMF的醇基团起着至关重要的作用.
- 这种反应途径为创建强大的TiO(2) - 聚合物复合材料提供了一种方法.
相关概念视频
Capacitor With A Dielectric
Parallel plate capacitors consist of two conducting plates separated by a certain distance. However, it is mechanically difficult to hold the large plates parallel to each other without actual contact. Hence, a dielectric layer is commonly placed between the plates, which provides an easy solution for holding the plates together with a small gap and increases the capacitance of the capacitor.
Dielectrics are non-conducting materials with no free or loosely bound electrons. When a dielectric is...
Dielectrics are non-conducting materials with no free or loosely bound electrons. When a dielectric is...
Dielectric Polarization in a Capacitor
The presence of a dielectric medium in a capacitor not only changes the voltage and capacitance but also affects the electric field. In general, dielectrics can be of two types: polar and nonpolar. In a polar dielectric, the positive and negative charges in the molecules are separated by a distance and hence have a permanent dipole moment. In contrast, no such charge separation exists in a nonpolar dielectric, however the nonpolar molecules get polarized in the presence of an external electric...
Susceptibility, Permittivity and Dielectric Constant
When placed in an external electric field, a dielectric material gets polarized. The charge density in the dielectric material is given by the sum of the bound and free charge densities, while the total charge density can also be written in terms of the total electric field. The bound charge density can be measured in terms of polarization, leading to the relationship between electric displacement and polarization.
Electrostatic Boundary Conditions in Dielectrics
When an electric field passes from one homogeneous medium to another, crossing the boundary between the two mediums imparts a discontinuity in the electric field. This results in electrostatic boundary conditions that depend on the type of mediums the field propagates through.
Consider a case where both the mediums across a boundary are two different dielectric materials. Recall that the electric field and electric displacement are proportional and related through the material's permittivity.
Consider a case where both the mediums across a boundary are two different dielectric materials. Recall that the electric field and electric displacement are proportional and related through the material's permittivity.


