用于储存的异原子替代碳支架的溶液相合成
Zhong Jin1, Zhengzong Sun, Lin J Simpson
1Department of Chemistry, and The Richard E. Smalley Institute for Nanoscale Science and Technology, Rice University, MS-222, 6100 Main Street, Houston, Texas 77005, United States.
Journal of the American Chemical Society
|October 9, 2010
概括
研究人员开发了一种使用,或制造碳材料的新方法. 这些材料表现出高表面积和改善的吸附,显示出储能应用的潜力.
科学领域:
- 材料科学 材料科学 材料科学
- 纳米技术 纳米技术
- 化学 化学 化学
背景情况:
- 开发先进的碳材料对于储能至关重要.
- 异构原子兴奋剂可以增强碳支架的特性.
- 现有的合成合碳材料的方法可能很复杂.
研究的目的:
- 报告一项新的原始和异原子替代碳支架的自下而上溶液相合成.
- 研究这些新型材料的结构和吸附特性.
- 探索,和替代对碳脚手架性能的影响.
主要方法:
- 一个溶液阶段过程,涉及加热含有机分子与金属在高沸的溶剂.
- 在合成过程中通过添加电友性试剂将异质原子纳入.
- 使用表面积分析和吸附异热法对得出的石墨板和石墨烯纳米片进行表征.
主要成果:
- 由3-5nm石墨烯纳米片组成的微米大小的石墨板的形成.
- 在碳结构中均分布的异构原子 (B,P,N) 的均分布.
- 实现了高表面积 (高达900 m2/g) 和增强的物理吸收能力.
- 在异原子替代支架上对吸附的强化结合能确定 (B:8.6,P:8.3,N:5.6kJ/mol).
结论:
- 开发的合成方法为高表面积碳支架提供了一个简单的途径.
- 不同原子的替代显著提高了吸附能力和结合能.
- 这些新型材料对储存和其他与能源相关的领域的应用非常有希望.
相关概念视频
Catalysis
The presence of a catalyst affects the rate of a chemical reaction. A catalyst is a substance that can increase the reaction rate without being consumed during the process. A basic comprehension of a catalysts’ role during chemical reactions can be understood from the concept of reaction mechanisms and energy diagrams.
Reduction of Alkenes: Asymmetric Catalytic Hydrogenation
Catalytic hydrogenation of alkenes is a transition-metal catalyzed reduction of the double bond using molecular hydrogen to give alkanes. The mode of hydrogen addition follows syn stereochemistry.
The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...
The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...
Reduction of Alkenes: Catalytic Hydrogenation
Alkenes undergo reduction by the addition of molecular hydrogen to give alkanes. Because the process generally occurs in the presence of a transition-metal catalyst, the reaction is called catalytic hydrogenation.
Metals like palladium, platinum, and nickel are commonly used in their solid forms — fine powder on an inert surface. As these catalysts remain insoluble in the reaction mixture, they are referred to as heterogeneous catalysts.
The hydrogenation process takes place on the surface of...
Metals like palladium, platinum, and nickel are commonly used in their solid forms — fine powder on an inert surface. As these catalysts remain insoluble in the reaction mixture, they are referred to as heterogeneous catalysts.
The hydrogenation process takes place on the surface of...
Hybridization of Atomic Orbitals II
sp3d and sp3d 2 Hybridization
Reduction of Alkynes to cis-Alkenes: Catalytic Hydrogenation
Introduction
Like alkenes, alkynes can be reduced to alkanes in the presence of transition metal catalysts such as Pt, Pd, or Ni. The reaction involves two sequential syn additions of hydrogen via a cis-alkene intermediate.
Like alkenes, alkynes can be reduced to alkanes in the presence of transition metal catalysts such as Pt, Pd, or Ni. The reaction involves two sequential syn additions of hydrogen via a cis-alkene intermediate.


