用于场效应晶体管的比提奥胺基聚合物半导体:合成,结构-属性相关性,电荷载体极性和设备稳定性
Xugang Guo1, Rocio Ponce Ortiz, Yan Zheng
1Department of Chemistry and the Materials Research Center, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208, United States.
Journal of the American Chemical Society
|January 7, 2011
概括
基于双胺 (BTI) 的新型聚合物为有机电子产品提供了改进的电荷传输. 某些BTI共聚物表现出极好的空气稳定性用于孔运输,这对于开发强大的有机场效应晶体管 (OFET) 至关重要.
科学领域:
- 材料科学 材料科学 材料科学
- 有机电子 有机电子
- 聚合物化学 聚合物化学
背景情况:
- 开发具有环境稳定的高流动性聚合物半导体是推动有机电子技术发展的关键.
- 基于比提奥胺 (BTI) 的聚合物正在探索其在有机场效应晶体管 (OFET) 中的潜力.
研究的目的:
- 合成和描述新的基于BTI的聚合物.
- 为了研究结合长度和分子量对载电荷移动性和设备性能的影响.
- 根据这些新聚合物,评估OFETs的空气稳定性.
主要方法:
- 合成具有不同结合长度的BTI同聚合物和共聚合物.
- 聚合物的特性,包括电荷载体的移动性.
- 在不同的架构中制造和测试有机场效应晶体管 (OFET).
- 评估设备在环境条件下的性能和稳定性.
主要成果:
- 在BTI共聚物中,对长度的增加将传输从电子主导转移到孔主导.
- 高分子量P(BTimR) 呈现出增强的电子流动性 (0.14 cm2/V·s),但空气稳定性较差.
- BTI共聚合物P2和P3在空气稳定性方面显著改善,可用于孔运输,可保持超过200天的流动性.
- P3实现了接近0.1cm2/V·s的孔移动性,与最先进的p型聚合物相美.
结论:
- 由于低的HOMOs,BTI构建块可以提高p型OFET的空气稳定性.
- 开发的BTI聚合物显示出稳定和高性能p型有机电子产品的前景.
- 通过喷墨模式成功制造了互补的逆变器.
更多相关视频
相关概念视频
Semiconductors
There is variation in the electrical conductivity of materials - metals, semiconductors, and insulators that are showcased with the help of the energy band diagrams.
Metals such as copper (Cu), zinc (Zn), or lead (Pb) have low resistivity and feature conduction bands that are either not fully occupied or overlap with the valence band, making a bandgap non-existent. This allows electrons in the highest energy levels of the valence band to easily transition to the conduction band upon gaining...
Metals such as copper (Cu), zinc (Zn), or lead (Pb) have low resistivity and feature conduction bands that are either not fully occupied or overlap with the valence band, making a bandgap non-existent. This allows electrons in the highest energy levels of the valence band to easily transition to the conduction band upon gaining...
Types of Semiconductors
Intrinsic semiconductors are highly pure materials with no impurities. At absolute zero, these semiconductors behave as perfect insulators because all the valence electrons are bound, and the conduction band is empty, disallowing electrical conduction. The Fermi level is a concept used to describe the probability of occupancy of energy levels by electrons at thermal equilibrium. In intrinsic semiconductors, the Fermi level is positioned at the midpoint of the energy gap at absolute zero. When...
Metal-Semiconductor Junctions
The contact of metal and semiconductor can lead to the formation of a junction with either Schottky or Ohmic behavior.
Schottky Barriers
Schottky barriers arise when a metal with a work function (Φm) contacts a semiconductor with a different work function (Φs). Initially, electrons transfer until the Fermi levels of the metal and semiconductor align at equilibrium. For instance, if Φm > Φs, the semiconductor Fermi level is higher than the metal's before contact. The semiconductor's...
Schottky Barriers
Schottky barriers arise when a metal with a work function (Φm) contacts a semiconductor with a different work function (Φs). Initially, electrons transfer until the Fermi levels of the metal and semiconductor align at equilibrium. For instance, if Φm > Φs, the semiconductor Fermi level is higher than the metal's before contact. The semiconductor's...
P-N junction
A p-n junction is formed when p-type and n-type semiconductor materials are joined together. At the interface of the p-n junction, holes from the p-side and electrons from the n-side begin to diffuse into the opposite sides due to the concentration gradient. This diffusion of carriers leads to a region around the junction where there are no free charge carriers, known as the depletion region. The charge density within the depletion region for the n-side and p-side can be described by the...
Field Effect Transistor
Field-effect transistors (FETs) are integral to electronic circuits and distinguished by their three-terminal setup: the gate, drain, and source. These transistors operate as unipolar devices, which utilize either electrons or holes as charge carriers, in contrast to bipolar transistors, which use both types of carriers. The primary function of the FET is to modulate the flow of these carriers from the source to the drain through a channel. The voltage difference between the gate and source...
Bipolar Junction Transistor
Bipolar Junction Transistors (BJTs) are essential elements in electronic circuits, playing a crucial role in the functionality of amplifiers, memories, and microprocessors. These transistors can be designed as NPN or PNP based on their doping patterns. They consist of three layers: the emitter, base, and collector. The configuration of these layers and their respective doping levels—with N-type or P-type impurities—define the transistor's type and its operational characteristics.
The structure...
The structure...


