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甲氧基的异构化:通过酸催化剂介导的分子内原子转移

Robert J Buszek1, Amitabha Sinha, Joseph S Francisco

  • 1Department of Chemistry, Purdue University, West Lafayette, Indiana 47907-2084, United States.

Journal of the American Chemical Society
|February 1, 2011
PubMed
概括

酸催化剂显著降低了CH(3) O的激素异构化到CH(2) OH.的激活能量. 硫酸催化提高了超过12个数量级的反应速率,使得禁止的气相激素反应.

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