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Hyperpolarized Xenon for NMR and MRI Applications
Published on: September 6, 2012
缺少的氧化物XeO2的合成及其对地球缺少的氧化物的影响
David S Brock1, Gary J Schrobilgen
1Department of Chemistry, McMaster University, Hamilton, Ontario L8S 4M1, Canada.
Journal of the American Chemical Society
|February 24, 2011
概括
研究人员通过水解合成了Xenon(IV) 氧化物 (XeO2). 这项研究揭示了 XeO2 .
科学领域:
- 无机化学 无机化学
- 固态化学 固态化学
- 频谱学是一种光谱学.
背景情况:
- 氧化物很少见,氧化物 (XeO2) 之前没有被描述.
- 了解异氧化物结构,可以深入了解贵气化学.
研究的目的:
- 合成和描述氧化物 (XeO2) 的Xenon(IV) 氧化物.
- 阐明 XeO2.2 的结构和粘合性质.
- 研究 XeO2 的结构对地质过程的影响.
主要方法:
- 四化物 (XeF4) 在水性硫酸中在0°C的水解.
- 拉曼光谱用于结构分析.
- 使用氧-18 (18O) 确认振动分配的同位素丰富研究.
主要成果:
- 成功合成了XeO2.2. 的合成.
- XeO2 呈现出一个延伸的结构,有氧桥梁的原子.
- 确定了一个局部方形平面的XeO4几何形状,与AX4E2 VSEPR理论一致.
- 为Xe(16) O2和Xe(18) O2.2分配了振动光谱.
结论:
- XeO2的表征扩展了已知的氧化的化学结构.
- 确定的结构支持在地质条件下与二氧化 (SiO2) 相互作用的理论.
- 这项研究可能会通过地过程来解释地球大气中的耗尽.
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