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Design, Synthesis, and Photochemical Properties of Clickable Caged Compounds
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通过化学修饰和外部刺激,在化物桥梁分子正方形中进行受控的分子内电子转移

Masayuki Nihei1, Yoshihiro Sekine, Naoki Suganami

  • 1Graduate School of Pure and Applied Sciences, University of Tsukuba, Tennodai 1-1-1, Tsukuba, Ibaraki 305-8571, Japan.

Journal of the American Chemical Society
|February 24, 2011
PubMed
概括

这项研究详细介绍了铁分子正方形的合成,这些正方形表现出独特的旋转过渡. 化合物1显示了两步电荷转移诱导自旋转换 (CTIST) 和光诱导转换,而化合物2和3则没有.

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