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Efficient Synthesis of Polyfunctionalized Benzenes in Water via Persulfate-promoted Benzannulation of α,β-Unsaturated Compounds and Alkynes
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1,2-二乙在四二中通过鲁比介导的树类型的降解

Sven Krieck1, Robert Kretschmer, Helmar Görls

  • 1Institut für Chemie/Bereich Anorganische Chemie, Karl-Franzens-Universität Graz, Schubertstrasse 1, A-8010 Graz, Austria.

Journal of the American Chemical Society
|April 21, 2011
PubMed
概括

研究人员合成了一种罕见的,高度反应性的有机化合物,[η(5) -{1,2-二-2,5-环二烯}) (1). 这种 pyrophoric 复合物可能是 Birch 类反应中的中间体,为有机金属化学提供了洞察力.

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