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在TiO2上的有机分子单层的生长和组织:catechol在anatase (101) 上

Li-Min Liu1, Shao-Chun Li, Hongzhi Cheng

  • 1Department of Chemistry, Princeton University, Princeton, New Jersey 08544, USA.

Journal of the American Chemical Society
|May 6, 2011
PubMed
概括

катехол分子在 anatase 二氧化表面上形成稳定的,一维的岛屿. 这种由分子构造变化驱动的自我组装是染料敏感太阳能电池的关键.

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The radical chain-growth polymerization mechanism consists of three steps: initiation, propagation, and termination of polymerization. The polymerization initiates when a free radical generated from the radical initiator adds to the unsaturated bond in the monomer. The unpaired electron of the free radical and one π electron in the unsaturated bond creates a σ bond between the free radical and the monomer. As a result, the other π electron in the unsaturated bond converts this species into the...