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Determination of the Photoisomerization Quantum Yield of a Hydrazone Photoswitch
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基于酸的旋转开关中的异构化机制:横向移动,旋转或分体化?

Shainaz M Landge1, Ekatarina Tkatchouk, Diego Benítez

  • 1Department of Chemistry, Dartmouth College, Hanover, New Hampshire 03755, USA.

Journal of the American Chemical Society
|May 19, 2011
PubMed
概括

化学控制的arylhydrazone分子开关可逆地在E和Z配置之间切换. 异构化可能是通过围绕C-N单键旋转而发生的,而不是C=N双键旋转.

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