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Updated: Jun 1, 2026

Synthesis of Monodisperse Cylindrical Nanoparticles via Crystallization-driven Self-assembly of Biodegradable Block Copolymers
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Synthesis of Monodisperse Cylindrical Nanoparticles via Crystallization-driven Self-assembly of Biodegradable Block Copolymers

Published on: June 20, 2019

圆柱体块共聚物微粒的端到端合和网络形成行为,具有晶体聚烯基芯

Siti F Mohd Yusoff1, Joe B Gilroy, Graeme Cambridge

  • 1School of Chemistry, University of Bristol, Bristol, United Kingdom BS8 1TS.

Journal of the American Chemical Society
|May 28, 2011
PubMed
概括

将半晶类同聚合物添加到圆柱状的小粒体中,会触发端到端的合,形成网络. 这一对于微粒组装至关重要的过程取决于添加的聚合物.

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The mechanism for anionic chain-growth polymerization involves initiation, propagation, and termination steps. In the initiation step, a nucleophilic anion, such as butyl lithium, initiates the polymerization process by attacking the π bond of the vinylic monomer. As a result, a carbanion, stabilized by the electron‐withdrawing group, is generated. The resulting carbanion acts as a Michael donor in the propagation step and attacks the second vinylic monomer, which acts as a Michael acceptor.
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