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Updated: Jun 1, 2026

Preparation and Use of Samarium Diiodide (SmI2) in Organic Synthesis: The Mechanistic Role of HMPA and Ni(II) Salts in the Samarium Barbier Reaction
12:22

Preparation and Use of Samarium Diiodide (SmI2) in Organic Synthesis: The Mechanistic Role of HMPA and Ni(II) Salts in the Samarium Barbier Reaction

Published on: February 4, 2013

在SmI2的反应中的催化Ni (II):基于Sm (II) 或Ni (0) 的化学反应?

Kimberly A Choquette1, Dhandapani V Sadasivam, Robert A Flowers

  • 1Department of Chemistry, Lehigh University, Bethlehem, Pennsylvania 18015, USA.

Journal of the American Chemical Society
|May 31, 2011
PubMed
概括

催化 (II) 盐通过降解为 (II) 增强萨马巴比埃反应. 这种(0) 然后通过氧化添加驱动反应,揭示了这种过程背后的已知化学成分.

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