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Updated: Jun 1, 2026

Isolating Free Carbenes, their Mixed Dimers and Organic Radicals
10:44

Isolating Free Carbenes, their Mixed Dimers and Organic Radicals

Published on: April 19, 2019

电子偏磁共振和计算研究从替代的N-异环碳素酸中衍生出来的基因

John C Walton1, Malika Makhlouf Brahmi, Julien Monot

  • 1School of Chemistry, EaStChem, University of St. Andrews, St. Andrews, Fife KY16 9ST, United Kingdom. jcw@st-andrews.ac.uk

Journal of the American Chemical Society
|May 31, 2011
PubMed
概括

第二代NHC-烯具有独特的激素化学成分. 它们的基显示出非局部自旋和明显的反应性,包括较慢的二分化和基驱动的反应,为有机基基化学提供了新的见解.

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Using Cyclic Voltammetry, UV-Vis-NIR, and EPR Spectroelectrochemistry to Analyze Organic Compounds11:44

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This lesson delves into the geometry of a radical, which is influenced by the electronic structure of the molecule. The principle is similar to that of a lone pair, where the unpaired electron influences the geometry at the radical center.
Accordingly, the structure of a trivalent radical lies between the geometries of carbocations and carbanions. An sp2-hybridized carbocation is trigonal planar, while an sp3-hybridized carbanion is trigonal pyramidal. Here, the difference in geometry is...
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Electron Paramagnetic Resonance (EPR) Spectroscopy: Organic Radicals

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