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Updated: Jun 1, 2026

Monitoring the Reductive and Oxidative Half-Reactions of a Flavin-Dependent Monooxygenase using Stopped-Flow Spectrophotometry
12:08

Monitoring the Reductive and Oxidative Half-Reactions of a Flavin-Dependent Monooxygenase using Stopped-Flow Spectrophotometry

Published on: March 18, 2012

对二甲基硫氧化减少酶催化中间体的光谱和电子结构研究:对电子和原子转移活性的影响

Regina P Mtei1, Ganna Lyashenko, Benjamin Stein

  • 1Department of Chemistry and Chemical Biology, The University of New Mexico, MSC03 2060, 1 University of New Mexico, Albuquerque, New Mexico 87131-0001, USA.

Journal of the American Chemical Society
|June 9, 2011
PubMed
概括

研究人员使用EPR,电子吸收和MCD光谱仪研究了二甲基硫氧化还原酶 (DMSOR) 中的偏磁性des-oxoMo(V) 中间体的电子结构. 结果揭示了它的低对称几何和金属中心轨道,对酶功能至关重要.

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