有碳心脏的金属宿主
Edwin C Constable1, Guoqi Zhang, Daniel Häussinger
1Department of Chemistry, University of Basel, Spitalstrasse 51, CH-4056 Basel, Switzerland. edwin.constable@unibas.ch
Journal of the American Chemical Society
|June 25, 2011
概括
-硫分子碗可以封装客人,如二甲或C60. 在碗上的替代组.
科学领域:
- 超分子化学 超分子化学
- 协调化学 协调化学
- 材料科学 材料科学 材料科学
背景情况:
- -硫集群为宿主-客人化学提供了独特的结构图案.
- 分子碗为选择性客体封装提供了明确的空洞.
研究的目的:
- 为了研究Ni(3) S(3) 基分子碗的客体封装能力.
- 确定吊替代剂如何影响主机-客户架构的组装.
- 探索这些复杂物在溶液中的动态行为.
主要方法:
- 单晶X射线衍射以确定固态结构.
- 一合成用于分子碗制备.
- 核磁共振 (NMR) 光谱用于溶液状态表征和定位研究.
主要成果:
- 基于Ni(3) S(3) 的分子碗成功捕获了二甲和C60的客体.
- 悬挂替代物 (纳夫他-2-甲基,基,乙基) 控制了1:1 (碗) 或2:1 (囊) 宿主-客户架构的形成,其中C60.
- 三合体复合体与溶液中的二度相似物 (CDCl3) 在平衡状态下存在.
- 核磁共振定位证实了1,2-二二-d4.4中纳夫二甲基替代宿主的1:1宿主-C60复合体.
结论:
- 证明了Ni(3) S(3) 分子碗的合成可访问性和结构多样性.
- 主机-客户端复杂化可以通过外围替代器进行调整,从而可以控制组装.
- 观察到不同聚合状态之间的溶液状态平衡,突出了动态的主机-客户互动.
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