以为基础的功能组作为罗塔xane形成的气结合模板.
Rehan Ahmed1, Andrea Altieri, Daniel M D'Souza
1School of Chemistry, EaStCHEM, University of St. Andrews, St. Andrews, Fife KY16 9ST, United Kingdom.
Journal of the American Chemical Society
|July 2, 2011
概括
研究人员利用含的功能组来制造 [2]rotaxanes. 这些通过结形成的新型结构显示出开发先进分子航天器和催化剂的潜力.
科学领域:
- 超分子化学 超分子化学
- 有机化学 有机化学
- 材料科学 材料科学 材料科学
背景情况:
- 罗塔克桑是机械互锁的分子,在纳米技术中具有潜在的应用.
- 结合是指导自组合的关键非共价相互作用.
- 含的功能组具有独特的电子和结构性质.
研究的目的:
- 探索使用含的功能组作为键受体在轮素合成.
- 研究由胺基,胺基和胺基组指导的螺纹轴周围的宏循环的自我组装.
- 通过X射线晶体学来描述由此产生的罗塔xane结构.
主要方法:
- 使用胺基,胺基和胺基作为键受体合成 [2] 胺基.
- 由线程上的胺基组和基于的功能组指导的组装.
- 通过X射线晶体学进行结构性表征.
主要成果:
- 成功合成 [2]rotaxanes,产量达到了60%.
- 识别多个相互组成的键,包括新的胺与胺相互作用.
- 在氧化物-胺胺轮中观察一种独特的以水为媒介的键网络.
结论:
- 以为基础的功能组是有效的键接受器,用于罗他素组装.
- 罗塔克桑的结构多样性可以通过不同的功能群来调整.
- 这些轮素有望在分子航天飞机和催化剂中的应用.
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