在双极场效应晶体管中的半导体是含有聚合物的亚二氧化-乙烯
Timea Dallos1, Dirk Beckmann, Gunther Brunklaus
1Max Planck Institute for Polymer Research, Mainz, Germany.
Journal of the American Chemical Society
|August 13, 2011
概括
研究人员开发了新的结合性共聚合物,PPTQT和PTTQT,其中包括亚二诺素和烯单元. PPTQT证明了双极半导体特性,标志着聚合物电子技术的突破.
科学领域:
- 材料科学 材料科学 材料科学
- 有机电子 有机电子
- 聚合物化学 聚合物化学
背景情况:
- 合聚合物对于有机电子设备至关重要.
- 开发具有平衡电荷传输 (两极性) 的材料是一个关键的挑战.
- 包括像乙烯这样的刚性π间隔器可以影响聚合物的电子性质.
研究的目的:
- 为了合成和表征含有亚二诺素和烯单元的新型联共聚物.
- 研究这些新材料的电子特性,特别是电荷载体的移动性.
- 探索聚合物骨干中三重键的潜力,以实现两极半导体行为.
主要方法:
- 合成两个结合共聚合物:PPTQT和PTTQT.
- 使用乙烯 π-spacer 连接亚醇诺素和芬部分.
- 材料性质的表征,包括电荷载体的移动性 (孔和电子).
主要成果:
- 成功合成了PPTQT和PTTQT共聚物.
- PPTQT的最大孔流动性为0.028cm2/Vs,电子流动性为0.042cm2/Vs.
- PPTQT代表了第一个在聚合物骨干中具有三重键的双极半导体材料.
结论:
- 开发的基于亚二基诺素的共聚物显示出有前途的半导体特性.
- 加入乙烯 π-spacer 和三重键是有效的实现双极电荷传输.
- 这些材料有可能用于先进的有机电子设备.
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