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五维不相称的结构的美丽石电解质[CaNd]2[Ga]2[Ga2O7]2的五维不相称的结构
Fengxia Wei1, Tom Baikie, Tao An
1Division of Materials Science & Engineering, Nanyang Technological University, Singapore.
Journal of the American Chemical Society
|August 18, 2011
概括
梅利利特类型的氧化物显示出作为固体氧化物燃料电池电解质的前景. 它们独特的晶体结构促进了氧离子的运动,提高了中间温度燃料电池的电解质性能.
科学领域:
- 材料科学 材料科学 材料科学
- 固态化学 固态化学
- 晶体学 晶体学是指结晶学.
背景情况:
- 目前正在探索使用美利类型的氧化物作为固氧化物燃料电池 (SOFC) 的电解质.
- 中温SOFCs需要具有高离子导电性的电解质.
研究的目的:
- 为了研究美利类型氧化物晶体结构.
- 了解使离子扩散成为可能的电解质应用的结构特征.
主要方法:
- [CaNd](2)[Ga](2)[Ga(2)O(7)](2) 的单晶使用光学浮带炉生长.
- 传输电子显微镜和粉末和单晶X射线衍射被用于结构分析.
主要成果:
- 离子阵列形成了一个带有扭曲五角形道的网络,容纳结构不合适.
- 确定了一个五维的超空间群对称性P(4−) 2(1)m(α,α,0) 00s((a−) a,0) 000,具有位移和职业调制.
- 结构优化,以容纳移动的氧气间歇器.
结论:
- 研究的氧化具有有利于离子扩散的结构特征.
- 这些材料的晶体化学定制可以增强离子导电性,优化它们作为中温固体氧化物燃料电池的电解质的性能.
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