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Updated: May 30, 2026

Controlled Photoredox Ring-Opening Polymerization of O-Carboxyanhydrides Mediated by Ni/Zn Complexes
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使用基于 (III) 的催化剂系统完美交替的CO2和化的共聚

Guang-Peng Wu1, Sheng-Hsuan Wei, Wei-Min Ren

  • 1State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian, People's Republic of China.

Journal of the American Chemical Society
|August 23, 2011
PubMed
概括

这项研究证明了使用新型催化剂从二氧化碳和化中有效合成可生物降解的聚碳酸盐. 该研究强调了选择性共聚合与缺电子环氧化物所面临的挑战.

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Overview
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Epoxidation of alkenes via oxidation with peroxy acids involves the conversion of a carbon–carbon double bond to an epoxide using the oxidizing agent meta-chloroperoxybenzoic acid, commonly known as MCPBA. Since the O–O bond of peroxy acids is very weak, the addition of electrophilic oxygen of peroxy acids to...
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