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Updated: May 29, 2026

Photochemical Oxidative Growth of Iridium Oxide Nanoparticles on CdSe@CdS Nanorods
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Photochemical Oxidative Growth of Iridium Oxide Nanoparticles on CdSe@CdS Nanorods

Published on: February 11, 2016

在极其基本的条件下通过使用Ru纳米粒子和2-phenyl-4-(1-naphthyl) quinolinium离子进行光催化进化

Yusuke Yamada1, Takamitsu Miyahigashi, Hiroaki Kotani

  • 1Department of Material and Life Science, Graduate School of Engineering, Osaka University, and ALCA, Japan Science and Technology Agency, Suita, Osaka 565-0871, Japan.

Journal of the American Chemical Society
|August 31, 2011
PubMed
概括

这项研究证明了光催化在基本条件下的演变,使用一种新催化剂系统. 这种新方法实现了与催化剂相当的高效率,为可持续的生产铺平了道路.

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Catalysis02:50

Catalysis

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Oxidation of Phenols to Quinones

In the presence of oxidizing agents, phenols are oxidized to quinones. Quinones can be easily reduced back to phenols using mild reducing agents. The electron-donating hydroxyl group enhances the reactivity of the aromatic ring, enabling oxidation of the ring even in the absence of an α hydrogen.
o-hydroxy phenols are oxidized to o-quinones and p-hydroxy phenols to p-quinones. Such redox reactions involve the transfer of two electrons and two protons. The reversible redox property is crucial in...
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Reduction of Alkenes: Asymmetric Catalytic Hydrogenation

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The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...
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The bonds formed in this reaction are stronger than the bonds broken, making it energetically favorable. The reaction follows a radical chain mechanism similar to radical halogenation reactions,...