相关实验视频
Updated: May 29, 2026

09:04
Fabrication of VB2/Air Cells for Electrochemical Testing
Published on: August 5, 2013
V2O5定碳纳米管用于增强的电化学能量存储
M Sathiya1, A S Prakash, K Ramesha
1CSIR Central Electrochemical Research Institute-Chennai Unit, CSIR-Madras Complex, Taramani, Chennai-600 113, India.
Journal of the American Chemical Society
|September 6, 2011
概括
这项研究开发了一种涂在碳纳米管 (CNT) 复合材料上的氧化 (V2O5),用于高性能储能. V2O5/CNTs材料显示出显著的容量贡献,提高了离子电池容量.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 纳米技术纳米技术
背景情况:
- 功能化的多壁碳纳米管 (CNTs) 提供高导电性和高表面积.
- 氧化 (V2O5) 是离子电池的一个有前途的阴极材料.
- 设计复合材料可以提高电化学性能.
研究的目的:
- 为了合成和描述用于电化学应用的V2O5/CNT复合物.
- 研究V2O5/CNT复合物与离子的电化学活性和容量贡献.
- 为了评估这种复合材料对高性能超级电容电极的潜力.
主要方法:
- 对氧化物进行受控的水解,以薄薄的V2O5层覆盖CNTs.
- 对V2O5/CNT复合物的离子活性进行电化学测试.
- 使用特拉萨蒂图和X射线光电子谱学 (XPS) 的分析.
主要成果:
- 复合V2O5/CNT显示了法拉代和电容容量的贡献.
- 在高速率 (1C) 时,电容行为占总容量的2/3 (2700C/g).
- XPS证实85%的瓦纳在放电后处于+4氧化状态,与电容贡献相一致.
结论:
- 纳米V2O5/CNTs复合物为Li(+) - 离子提供了一个短的扩散路径,并容易进入氧化还氧化中心.
- CNT的高导电性提高了整体电化学性能.
- 复合结构显示出高功率和能量密度,适用于先进的超级电容电极.
相关概念视频
Energy Stored in Capacitors
A parallel plate capacitor, when connected to a battery, develops a potential difference across its plates. This potential difference is key to the operation of the capacitor, as it determines how much electrical energy the capacitor can store.
By integrating the equation that relates voltage and current in a capacitor, one can derive an equation for the voltage across the capacitor at any given time. This equation is crucial in understanding and predicting the behavior of capacitors in...
By integrating the equation that relates voltage and current in a capacitor, one can derive an equation for the voltage across the capacitor at any given time. This equation is crucial in understanding and predicting the behavior of capacitors in...
Electrochemical Cells
Electrochemical cells are systems that convert chemical energy into electrical energy or use electrical energy to drive chemical reactions. They consist of two electrodes in contact with an electrolyte, where redox reactions enable electron transfer. Most electrochemical cells include two half-cells connected by an external wire for electron flow and a salt bridge for ion flow. The salt bridge contains an electrolyte solution and maintains charge neutrality by allowing ions—not electrons—to...
Voltaic/Galvanic Cells
Spontaneous Chemical Reactions
Spontaneous redox reactions occur abundantly in nature. The chemical reaction occurring in a disposable AA battery powering our remote controls is one such example of a spontaneous redox reaction. Another example is the immersion of coiled copper wire into an aqueous silver nitrate solution. The reaction shows a gradual, visually impressive color change from colorless to bright blue and the formation of a grey precipitate on the copper wire. In this experiment,...
Spontaneous redox reactions occur abundantly in nature. The chemical reaction occurring in a disposable AA battery powering our remote controls is one such example of a spontaneous redox reaction. Another example is the immersion of coiled copper wire into an aqueous silver nitrate solution. The reaction shows a gradual, visually impressive color change from colorless to bright blue and the formation of a grey precipitate on the copper wire. In this experiment,...
Energy Stored in a Capacitor
When an archer pulls the string in a bow, he saves the work done in the form of elastic potential energy. When he releases the string, the potential energy is released as kinetic energy of the arrow. A capacitor works on the same principle in which the work done is saved as electric potential energy. The potential energy (UC) could be calculated by measuring the work done (W) to charge the capacitor.
Batteries and Fuel Cells
A battery is a galvanic cell that is used as a source of electrical power for specific applications. Modern batteries exist in a multitude of forms to accommodate various applications, from tiny button batteries such as those that power wristwatches to the very large batteries used to supply backup energy to municipal power grids. Some batteries are designed for single-use applications and cannot be recharged (primary cells), while others are based on conveniently reversible cell reactions that...

