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放松但非常紧的迪安萨金属cyclophanes

Pau Farràs1, Francesc Teixidor, Isabel Rojo

  • 1Institut de Ciència de Materials de Barcelona (ICMAB-CSIC), Campus de la U.A.B., E-08193 Bellaterra, Spain.

Journal of the American Chemical Society
|September 13, 2011
PubMed
概括

新的cobaltabisdicarbollidephanes具有独特的结构和电子特性. 这些金属cyclophanes显示氨酸捐赠者和受体之间的协同作用,影响他们的反应性和通信通路.

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Structure of Conjugated Dienes

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The Diels–Alder reaction brings together a diene and a dienophile to form a six-membered ring. Both components have unique characteristics that influence the rate of the reaction.
Characteristics of the diene
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The simplest example of a diene is 1,3-butadiene, an acyclic conjugated π system. At room temperature, the molecule exists as a mixture of s-cis and s-trans conformers by virtue of rotation around the carbon–carbon single bond. Although the s-trans isomer is more stable, the...
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