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在pd催化转化三甲基酸到甲基化物过程中,有证据表明在现场发生催化剂修饰

Thomas J Maimone1, Phillip J Milner, Tom Kinzel

  • 1Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, United States.

Journal of the American Chemical Society
|October 18, 2011
PubMed
概括

这项研究研究了催化反应,将三甲酸转化为化物. 它发现,C-F的减小消除受到电子丰富的基团的阻碍,这表明涉及到一个修饰的联结体.

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