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Preparation of a Corannulene-functionalized Hexahelicene by Copper(I)-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units
09:35

Preparation of a Corannulene-functionalized Hexahelicene by Copper(I)-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units

Published on: September 18, 2016

结构阐明和区域选择性功能化一个尚未探索的碳化物集群金属 Sc2C2@C(s) ((6) -C82

Xing Lu1, Koji Nakajima, Yuko Iiduka

  • 1Life Science Center of Tsukuba Advanced Research Alliance, University of Tsukuba, Tsukuba, Ibaraki 305-8577, Japan.

Journal of the American Chemical Society
|October 26, 2011
PubMed
概括

这项研究使用光谱学和晶体学确定了一种新的碳化物金属,Sc(2)C(2)@C(s) -C(82). 研究了其化学反应性和区域选择性添加反应,揭示了其添加物的增强稳定性.

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