经过乙烯保护的器官金色集群.
Prasenjit Maity1, Hironori Tsunoyama, Miho Yamauchi
1Catalysis Research Center, Hokkaido University, Nishi 10, Kita 21, Sapporo 001-0021, Japan.
Journal of the American Chemical Society
|November 16, 2011
概括
研究人员通过将乙烯与黄金集群结合,创造了新的器官黄金集群. 这一突破为金纳米材料提供了一个新的类别,具有定义的组成,由质谱学证实.
科学领域:
- 纳米材料科学 科学 纳米材料科学
- 有机金属化学 有机金属化学
- 表面化学 表面化学
背景情况:
- 单层保护的黄金集群在催化和医学中至关重要.
- 以前的方法往往导致较少定义的集群组成.
- 开发具有共价Au-C键的器官黄金集群是一个合成挑战.
研究的目的:
- 合成一种新型的有机黄金集群,具有直接的黄金-碳共价键.
- 描述这些新型星团的组成和稳定性.
- 探索乙烯作为黄金集群稳定器的配体的潜力.
主要方法:
- 通过聚烯立 (PVP) 稳定黄金集群的合成.
- 乙烯 (PhCCH) 与PVP稳定黄金集群的结合.
- 使用矩阵辅助激光吸附离子化质谱法 (MALDI-MS) 进行表征.
主要成果:
- 成功合成了具有Au-C共价键的单层保护黄金集群 (organogold集群).
- 通过MALDI-MS.识别有机金 (Au:C(2) Ph) 集群的稳定成分.
- 展示乙烯作为有效的连接体,用于创建稳定,共功能化的黄金集群.
结论:
- 已经合成了一种具有Au-C共价键的新型器官黄金集群类.
- 这项研究提供了第一个质谱学证据,证明稳定的有机黄金集群组成.
- 这项工作为设计功能化的金纳米材料开辟了新的途径.
相关概念视频
Protecting Groups for Aldehydes and Ketones: Introduction
Protecting groups are compounds that can bind to a specific functional group in the presence of other functional groups to protect them from undesired chemical reactions. These compounds can selectively bind to particular functional groups and advance chemoselective reactions in polyfunctional systems (Figure 1). After the functional group has served its purpose, it is removed by reacting it with specific compounds.
Acetals and Thioacetals as Protecting Groups for Aldehydes and Ketones
Acetals are formed by reacting two equivalents of alcohol with carbonyl compounds like aldehydes or ketones. Acetals are unaffected by bases, nucleophiles, oxidizing agents, and reducing agents. They serve as protecting groups for aldehydes and ketones. Acetals can be easily formed and also easily removed via mild acid hydrolysis.
In the presence of multiple functional groups, when selective reduction of one group over the other is desired, groups like aldehydes and ketones that form acetals...
In the presence of multiple functional groups, when selective reduction of one group over the other is desired, groups like aldehydes and ketones that form acetals...
Protection of Alcohols
This lesson delves into the concept of protection and deprotection of a functional group fundamental to synthetic organic chemistry. These phenomena are explained in the context of aliphatic and aromatic alcohols.
Protection
It defines a protecting group as the masking agent to make the more reactive species inert to a given set of conditions. This concept is depicted via the illustration of liquid flow through different outlets in an assembly of pipes. The analogy helps to understand the role...
Protection
It defines a protecting group as the masking agent to make the more reactive species inert to a given set of conditions. This concept is depicted via the illustration of liquid flow through different outlets in an assembly of pipes. The analogy helps to understand the role...
Properties of Organometallic Compounds
Organometallic compounds are compounds that contain a carbon–metal bond. Carbon belongs to an organyl group like alkyl, aryl, allyl, or benzyl groups. The metal can be from Group I or Group II of the periodic table, a transition metal, or a semimetal.
Alkynes to Aldehydes and Ketones: Hydroboration-Oxidation
Introduction
One of the convenient methods for the preparation of aldehydes and ketones is via hydration of alkynes. Hydroboration-oxidation of alkynes is an indirect hydration reaction in which an alkyne is treated with borane followed by oxidation with alkaline peroxide to form an enol that rapidly converts into an aldehyde or a ketone. Terminal alkynes form aldehydes, whereas internal alkynes give ketones as the final product.
One of the convenient methods for the preparation of aldehydes and ketones is via hydration of alkynes. Hydroboration-oxidation of alkynes is an indirect hydration reaction in which an alkyne is treated with borane followed by oxidation with alkaline peroxide to form an enol that rapidly converts into an aldehyde or a ketone. Terminal alkynes form aldehydes, whereas internal alkynes give ketones as the final product.
ortho–para-Directing Activators: –CH3, –OH, –⁠NH2, –OCH3
All ortho–para directors, excluding halogens, are activating groups. These groups donate electrons to the ring, making the ring carbons electron-rich. Consequently, the reactivity of the aromatic ring towards electrophilic substitution increases. For instance, the nitration of anisole is about 10,000 times faster than the nitration of benzene. The electron-donating effect of the methoxy group in anisole activates the ortho and para positions on the ring and stabilizes the corresponding...


