添加剂对由高效有机太阳能电池的活性层组成的溶液相聚合物的形态的影响
Sylvia J Lou1, Jodi M Szarko, Tao Xu
1Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208, USA.
Journal of the American Chemical Society
|December 1, 2011
概括
二度公 (DIO) 添加剂通过溶解烯受体聚合物来改善有机太阳能电池. 这可以更好地与供体聚合物混合,优化膜结构和性能.
科学领域:
- 材料科学 材料科学 材料科学
- 有机电子 有机电子
- 太阳能光伏发电是如何实现的
背景情况:
- 加工添加剂对于有机光伏 (OPV) 设备的性能至关重要.
- 添加剂影响活性层形态的确切机制尚不清楚.
研究的目的:
- 阐明二多 (DIO) 在修改 PTB7:PC(71) BM活性层的形态学中的作用.
- 了解OPV处理期间的供体和受体材料的聚合行为.
主要方法:
- 利用X射线散射技术来分析材料聚合.
- 在模拟加工条件下研究DIO对聚合物和富勒烯衍生物混合物的影响.
主要成果:
- 发现DIO可以选择性地溶解富勒烯受体的聚合物,PC(71) BM.
- 这种溶解促进了PC(71) BM在PTB7供体聚合物域中的插入.
- 观察到优化的域大小和改进的PTB7-PC(71) BM接口特征.
结论:
- 双多干作为一种选择性溶剂,控制烯聚合.
- 添加剂的作用导致有机光伏系统的增强形态和提高性能.
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