一个新的和可充电电池类别,基于和硫作为正极电极
Ali Abouimrane1, Damien Dambournet, Karena W Chapman
1Chemical Sciences and Engineering Division, Argonne National Laboratory, Argonne, Illinois 60439, United States. Abouimrane@anl.gov
Journal of the American Chemical Society
|February 28, 2012
概括
新的和硫阴极为和电池提供了高性能. 这些材料提供可调节性质和高压循环,促进电动汽车和智能电网的储能.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 离子和离子电池对于现代能源存储至关重要.
- 开发高容量,稳定的阴极材料仍然是一个关键的挑战.
- 现有的基于硫的阴极面临着稳定性和导电性的问题.
研究的目的:
- 引入新的和-硫 (Se(x) S(y)) 阴极材料.
- 研究 (Li) 和 (Na) 插入这些电极的结构机制.
- 评估这些新材料在储能应用中的电化学性能和潜力.
主要方法:
- 和硫阴极材料的合成和表征.
- 和Na的插入/提取的电化学测试.
- 对分布函数 (PDF) 分析以了解结构机制.
主要成果:
- (Se) 电极在和纳阳极上都显示出有前途的电化学性能.
- 混合Se(x) S(y) 系统提供可调节的电极特性,平衡能力和导电性.
- 在高电压 (高达4.6V) 时,Se和Se{x}S{y}电极表现出稳定的循环.
- 与硫基电池相比,这些材料实现了较高的体积能量密度.
结论:
- 和-硫化合物代表了先进电池的新一类可行的正极材料.
- Se(x) S(y) 的可调节性允许优化电极性能.
- 高压稳定性和能量密度使得这些材料对电动汽车和电网存储非常有希望.
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