由铁促进的沉积物中有机物质的保存
Karine Lalonde1, Alfonso Mucci, Alexandre Ouellet
1GEOTOP and Department of Chemistry and Biochemistry, Concordia University, 7141 Sherbrooke Street West, Montreal, Quebec H4B 1R6, Canada.
Nature
|March 9, 2012
概括
沉积物中的铁与有机碳结合,在"生的水槽"中保存它. 这种关联对于长期的碳储存和全球生物地球化学循环至关重要.
科学领域:
- 地质化学 地质化学
- 生物地质化学生物地质化学
- 环境科学 环境科学
背景情况:
- 铁和有机碳的生物地球化学循环是相互关联的.
- 有机配体控制海洋中溶解的铁,而铁相保留土壤中的有机碳.
- 铁在保护海洋沉积物中的有机物质中的作用尚不清楚.
研究的目的:
- 在各种沉积物中量化与反应性铁相相关的有机碳.
- 评估铁-有机碳相互作用对海洋环境中的有机物质保存的重要性.
主要方法:
- 在各种沉积物类型上使用一种以前用于土壤的铁还原方法.
- 分析了来自各种沉积环境的沉积物.
主要成果:
- 沉积物中大约21.5%±8.6%的有机碳直接与反应性铁相结合.
- 估计全球质量为 (19-45) × 10^15克的有机碳由于铁协会而在海洋沉积物中保存.
- 有机碳铁结合通过共同沉和/或直接化而形成.
结论:
- 铁与有机碳的结合,极大地促进了沉积物中的有机物质的保存.
- 反应性铁相作为有机碳的长期"生水槽".
- 这些相互作用是全球碳,氧和硫循环中的关键因素.
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