纳夫托[2,1-b:6,5-b']二:一种可用于溶液处理单晶有机场效应晶体管具有高孔移动性的多功能动图
Chikahiko Mitsui1, Junshi Soeda, Kazumoto Miwa
1Department of Chemistry, School of Science, The University of Tokyo, Tokyo, Japan.
Journal of the American Chemical Society
|March 15, 2012
概括
新的纳夫托二衍生物作为高性能p型半导体. 这些材料可以在有机电子产品中实现高效的电荷传输,在晶体管中实现高流动性和开/关比.
科学领域:
- 有机电子学有机电子学
- 材料科学是一种材料科学.
- 半导体物理 半导体物理
背景情况:
- 开发高效的p型有机半导体对于推进有机电子技术至关重要.
- 溶液加工有机场效应晶体管 (OFET) 提供了具有成本效益的制造方法.
研究的目的:
- 引入新型纳夫托[2,1-b:6,5-b']多衍生物作为p型半导体.
- 为了研究它们在溶液处理的单晶有机场效应晶体管中的性能.
主要方法:
- 纳夫托[2,1-b:6,5-b']二衍生物的合成.
- 用溶液处理的单晶有机场效应晶体管的制造和表征.
- 分析电荷传输特性和与分子结构和包装的相关性.
主要成果:
- 实现高孔机动性高达3.6厘米(2) V(-1) s(-1).
- 证明了高的开/关电流比率 (我打开/我关闭).
- 性能归因于密集的晶体包装,大的分子间π轨道重叠,以及由于氧原子半径的小重组能量.
结论:
- 纳[2,1-b:6,5-b']二衍生物代表了一类有前途的p型半导体.
- 分子设计为有机电子应用提供了出色的电荷传输特性.
- 溶液加工使高性能有机晶体管的高效制造成为可能.
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