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相关概念视频

Catalysis02:50

Catalysis

The presence of a catalyst affects the rate of a chemical reaction. A catalyst is a substance that can increase the reaction rate without being consumed during the process. A basic comprehension of a catalysts’ role during chemical reactions can be understood from the concept of reaction mechanisms and energy diagrams.
Catalysis01:27

Catalysis

Catalysis influences the rate of chemical reactions by providing an alternative reaction pathway with lower activation energy. A catalyst speeds up a reaction, but it is not consumed during the process. The fundamental principle of catalysis is the ability of a catalyst to alter the reaction mechanism, often introducing a more efficient pathway than the uncatalyzed process.In a catalyzed reaction, the catalyst participates directly in the reaction mechanism. It interacts with reactants to form...
Heterogeneous Catalysis01:22

Heterogeneous Catalysis

Heterogeneous catalysis involves a catalyst in a different phase from the reactants. It is a process where the catalyst and the reactants are in distinct phases, typically solid and gas or liquid.Most heterogeneous catalysts are metals, metal oxides, or acids. The list includes transition metals like iron (Fe), cobalt (Co), nickel (Ni), palladium (Pd), platinum (Pt), chromium (Cr), manganese (Mn), tungsten (W), silver (Ag), and copper (Cu). These metals possess partially vacant d orbitals that...
Oxidative Cleavage of Alkenes: Ozonolysis01:46

Oxidative Cleavage of Alkenes: Ozonolysis

In ozonolysis, ozone is used to cleave a carbon–carbon double bond to form aldehydes and ketones, or carboxylic acids, depending on the work-up.
Ozone is a symmetrical bent molecule stabilized by a resonance structure.
Turnover Number and Catalytic Efficiency01:19

Turnover Number and Catalytic Efficiency

The turnover number of an enzyme is the maximum number of substrate molecules it can transform per unit time. Turnover numbers for most enzymes range from 1 to 1000 molecules per second. Catalase has the known highest turnover number, capable of converting up to 2.8×106 molecules of hydrogen peroxide into water and oxygen per second. Lysozyme has the lowest known turnover number of half a molecule per second.
Chymotrypsin is a pancreatic enzyme that breaks down proteins during digestion. The...

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相关实验视频

Updated: May 24, 2026

Synthesis of Platinum-nickel Nanowires and Optimization for Oxygen Reduction Performance
09:02

Synthesis of Platinum-nickel Nanowires and Optimization for Oxygen Reduction Performance

Published on: April 27, 2018

在酸氧化演化催化剂中的结构-活性相关性.

D Kwabena Bediako1, Benedikt Lassalle-Kaiser, Yogesh Surendranath

  • 1Department of Chemistry, 6-335, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, USA.

Journal of the American Chemical Society
|March 16, 2012
PubMed
概括

阳极激活大大提高了玻酸氧演化催化剂的性能. 这涉及结构转变和转向更高的氧化状态,包括Ni(IV),挑战了以前的催化剂效率假设.

科学领域:

  • 电化学 电化学 电化学
  • 材料科学 材料科学 材料科学
  • 催化剂是一种催化剂.

背景情况:

  • 氧进化反应 (OER) 对能量转化至关重要.
  • 基于的催化剂被广泛研究为OER.
  • 了解催化剂结构与活性关系是提高效率的关键.

研究的目的:

  • 研究酸 (Ni-B(i)) 薄膜在阳极激活后的结构和氧化状态的变化.
  • 为了将这些变化与增强的氧气进化催化活性相关联.
  • 挑战关于β-NiOOH在OER中的效率的现有观念.

主要方法:

  • 在现场的X射线吸收光谱 (XAS) 包括X射线吸收近边缘结构 (XANES) 和扩展的X射线吸收细结构 (EXAFS).
  • 库洛米度测量. 库洛米度测量.
  • 电沉积Ni-B (i) 薄膜的电化学特性.

主要成果:

  • 阳极激活显著增加了Ni-B的催化速率.
  • 活性膜具有较高的平均氧化状态 (+3.6),具有显著的Ni (IV) 存在.
  • 激活片显示边缘共享NiO6八面体中的双氧/桥中心结构,而非激活片显示Jahn-Teller扭曲的Ni6中心.

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Chemical Precipitation Method for the Synthesis of Nb2O5 Modified Bulk Nickel Catalysts with High Specific Surface Area
08:13

Chemical Precipitation Method for the Synthesis of Nb2O5 Modified Bulk Nickel Catalysts with High Specific Surface Area

Published on: February 19, 2018

Synthesis and Performance Characterizations of Transition Metal Single Atom Catalyst for Electrochemical CO2 Reduction
10:57

Synthesis and Performance Characterizations of Transition Metal Single Atom Catalyst for Electrochemical CO2 Reduction

Published on: April 10, 2018

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Last Updated: May 24, 2026

Synthesis of Platinum-nickel Nanowires and Optimization for Oxygen Reduction Performance
09:02

Synthesis of Platinum-nickel Nanowires and Optimization for Oxygen Reduction Performance

Published on: April 27, 2018

Chemical Precipitation Method for the Synthesis of Nb2O5 Modified Bulk Nickel Catalysts with High Specific Surface Area
08:13

Chemical Precipitation Method for the Synthesis of Nb2O5 Modified Bulk Nickel Catalysts with High Specific Surface Area

Published on: February 19, 2018

Synthesis and Performance Characterizations of Transition Metal Single Atom Catalyst for Electrochemical CO2 Reduction
10:57

Synthesis and Performance Characterizations of Transition Metal Single Atom Catalyst for Electrochemical CO2 Reduction

Published on: April 10, 2018

结论:

  • 增强的OER活性与结构和氧化状态的变化有关,特别是Ni的形成.
  • 这些发现表明,激活的Ni-B(i) 薄膜经历了类似于β-NiOOH到玛-NiOOH转换的转换.
  • 这项研究挑战了β-NiOOH作为优越的氧气演化催化剂阶段的既定观点.