染料分子结构装置在Ru(II) 敏感剂中的开放电路电压相关性,用于染料敏感的太阳能电池的异构三酸
Kuan-Lin Wu1, Cheng-Hsuan Li, Yun Chi
1Department of Chemistry and Low Carbon Energy Research Center, National Tsing Hua University, Hsinchu 30013, Taiwan.
Journal of the American Chemical Society
|April 18, 2012
概括
扩展结合的新型鲁丁 (II) 敏感剂在染料敏感太阳能电池 (DSC) 中表现出高性能. 这些新型染料没有硫酸连接体,为有效的太阳能转化提供了一个有前途的原型.
科学领域:
- 材料科学 材料科学 材料科学
- 太阳能光伏发电是如何实现的
- 协调化学 协调化学
背景情况:
- 染料敏感太阳能电池 (DSC) 是一个有前途的可再生能源技术.
- (II) 复合物被广泛用作DSC中的敏感剂.
- 改善光收集和电荷转移对于提高DSC效率至关重要.
研究的目的:
- 为了合成新型的异体质,双三酸 ((II) 敏感剂与 π 结合的悬挂组.
- 评估这些新型传感器在DSC中的光伏性能.
- 研究分子结构,重组动力学和设备性能之间的关系.
主要方法:
- 合成二碳二二酸盐和2,6-bis(5-pyrazolyl) 二连接物.
- (II) 敏感剂的制备和表征 (TF-11-14).
- 在模拟阳光下制造和测试DSC (AM1.5G).
- 用光谱和动态测量来探测重组过程.
主要成果:
- 与参考N749设备相比,合成的TF染料在DSC中表现出色.
- 感应器TF-12实现了9.21%的转换效率,光电流为19.0 mA cm-2,V (OC) 为0.71 V,填充因子为0.68.
- 在TF染料中增加的合增强了光采集和光伏能力.
- 在设备开放电路电压和细胞电子寿命之间发现了相关性.
结论:
- 新的二三酸 (ruthenium) 敏感剂与 π 结合的悬挂组对 DSCs 具有高度效率.
- 在没有硫酸连体的情况下可以实现高效率,这挑战了以前的假设.
- 双碳氧配置作为一个有价值的原型,用于设计未来的高性能 (II) 敏感剂.
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