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Updated: May 20, 2026

Self-assembling Morphologies Obtained from Helical Polycarbodiimide Copolymers and Their Triazole Derivatives
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Published on: February 7, 2017

合成和自我组装过程的单一功能甲[7]urilil

Brittany Vinciguerra1, Liping Cao, Joe R Cannon

  • 1Department of Chemistry and Biochemistry, University of Maryland , College Park, Maryland 20742, United States.

Journal of the American Chemical Society
|July 18, 2012
PubMed
概括

我们使用构建模块方法开发了功能化的循环德克斯特林类CB[7]衍生物. 这些新型CB[7]化合物具有较高的水溶性,可以溶解像阿尔本达这样的溶性较差的药物.

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Cationic Chain-Growth Polymerization: Mechanism00:57

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The cationic polymerization mechanism consists of three steps: initiation, propagation, and termination. In the initiation step of the polymerization process, the π bond of a monomer gets protonated by the Lewis acid catalyst, which is formed from boron trifluoride and water. The protonation of the π bond generates a carbocation stabilized by the electron‐donating group. In the propagation step, the π bond of the second monomer acts as a nucleophile and attacks the generated carbocation,...