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Updated: May 20, 2026

Combining Solid-state and Solution-based Techniques: Synthesis and Reactivity of Chalcogenidoplumbates(II or IV)
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Combining Solid-state and Solution-based Techniques: Synthesis and Reactivity of Chalcogenidoplumbates(II or IV)

Published on: December 29, 2016

通过Pd-Pd键裂解连接双核Pd (III) 和单核Pd (IV) 化学

David C Powers1, Eunsung Lee, Alireza Ariafard

  • 1Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, Massachusetts 02138, USA.

Journal of the American Chemical Society
|July 19, 2012
PubMed
概括

用三甲基化试剂氧化复合物产生单核复合物. 这通过氧化碎片化途径发生,揭示了对化学中的核性效应的见解.

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A bond can be broken either by heterolytic bond cleavage to form ions or homolytic bond cleavage to yield radicals. A fishhook arrow is used to represent the motion of a single electron in homolytic bond cleavage. There are two main sources from which radicals can be formed:
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