通过与氧气合金,增加铁甲的带隙
Jun Hu1, Yanning Zhang, Matt Law
1Department of Physics and Astronomy, University of California, Irvine, California 92697-4575, USA.
Journal of the American Chemical Society
|July 26, 2012
概括
用氧杂质修改铁 (FeS(2) 增强了其带隙,使其适合高效的太阳能电池. 这种结构修改改善了光伏性能和设备性能.
科学领域:
- 材料科学 材料科学 材料科学
- 固态物理 固态物理
- 可再生能源可再生能源是可再生能源.
背景情况:
- 铁化 (FeS(2)) 是一个有前途的光伏材料,但在太阳能转换方面具有不理想的频段差距.
- 提高铁甲的带隙对于提高太阳能电池效率至关重要.
研究的目的:
- 为了研究氧气替代铁酸盐对其电子和结构性质的影响.
- 评估氧化铁矿在先进太阳能电池应用中的潜力.
主要方法:
- 系统密度函数理论 (DFT) 的计算.
- 对材料属性的模型分析.
- 热力学稳定性和相隔分析.
主要成果:
- 在FeS(2) 中将大约10%的硫原子替换为氧原子,将带间隙增加到1.2-1.3 eV.
- 氧的替代是外热的,促进稳定的FeS(2-x) O(x) 合金,防止相位分离.
- 由此产生的合金对太阳能电池具有有利的特性,包括理想的带隙,高光学吸收性和低电子有效质量.
结论:
- 用氧气合的铁化 (FeS(2-x) O(x)) 合金对下一代太阳能电池具有前景.
- 这些材料在以岩为基础的异质连接太阳能电池中提供了高光电压和设备效率的潜力.
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