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从低价值的胺复合物中减少消除胺

Patrick S Hanley1, Seth L Marquard, Thomas R Cundari

  • 1Department of Chemistry, University of Illinois at Urbana-Champaign, Urbana, Illinois 61801, USA.

Journal of the American Chemical Society
|September 1, 2012
PubMed
概括

大量的N- heterocyclic carbene (NHC) 连接体促进了催化降解消除以形成胺. 电子捐赠胺基和NHC连接体加快反应,而固态散体减缓它们,通过协调的途径进行.

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