在比斯穆特氧硫化物Bi4O4S3中的散装超导性
Shiva Kumar Singh1, Anuj Kumar, Bhasker Gahtori
1Quantum Phenomena and Applications Division, National Physical Laboratory (CSIR), Dr. K. S. Krishnan Road, New Delhi 110012, India.
Journal of the American Chemical Society
|September 26, 2012
概括
我们合成了Bi ((4) O ((4) S ((3)),并证实它是一种散装超导体,过渡温度为4.4K.这一发现排除了杂质驱动的超导性,为分层硫化物研究开辟了新的途径.
科学领域:
- 材料科学 材料科学 材料科学
- 凝聚物质物理学 凝聚物质物理学
- 固态化学 固态化学
背景情况:
- 最近的报道表明,硫化物层层的超导性.
- 生物4) O4) S3) 是超导研究的潜在候选者.
研究的目的:
- 使用真空封装技术合成Bi(4) O(4) S(3).
- 描述它的超导特性.
- 调查超导电的起源.研究超导电的起源.
主要方法:
- 在500°C的真空封装合成.
- 交流/直流磁化测量.交流/直流磁化测量.
- 同热磁化 (M-H) 和磁传输测量.
主要成果:
- 合成的Bi(4)O(4)S(3) 具有四角形结构 (I4/mmm).
- 证实了大量超导,过渡温度 (T ((c)) 为4.4K.
- 确定较低的临界场 (H(c1)) ~15 Oe和较高的临界场 (H(c2) ((0)) ~31 kOe.
结论:
- 生物4) O4) S3) 呈现大量超导性,而不是由杂质驱动的.
- 这些发现支持进一步探索层叠硫化物的超导性.
相关概念视频
Superconductor
A substance that reaches superconductivity, a state in which magnetic fields cannot penetrate, and there is no electrical resistance, is referred to as a superconductor. In 1911, Heike Kamerlingh Onnes of Leiden University, a Dutch physicist, observed a relation between the temperature and the resistance of the element mercury. The mercury sample was then cooled in liquid helium to study the linear dependence of resistance on temperature. It was observed that, as the temperature decreased, the...
Types Of Superconductors
A superconductor is a substance that offers zero resistance to the electric current when it drops below a critical temperature. Zero resistance is not the only interesting phenomenon as materials reach their transition temperatures. A second effect is the exclusion of magnetic fields. This is known as the Meissner effect. A light, permanent magnet placed over a superconducting sample will levitate in a stable position above the superconductor. High-speed trains that levitate on strong...
Colors and Magnetism
Color in Coordination Complexes
When atoms or molecules absorb light at the proper frequency, their electrons are excited to higher-energy orbitals. For many main group atoms and molecules, the absorbed photons are in the ultraviolet range of the electromagnetic spectrum, which cannot be detected by the human eye. For coordination compounds, the energy difference between the d orbitals often allows photons in the visible range to be absorbed and emitted, which is seen as colors by the human eye.
When atoms or molecules absorb light at the proper frequency, their electrons are excited to higher-energy orbitals. For many main group atoms and molecules, the absorbed photons are in the ultraviolet range of the electromagnetic spectrum, which cannot be detected by the human eye. For coordination compounds, the energy difference between the d orbitals often allows photons in the visible range to be absorbed and emitted, which is seen as colors by the human eye.
Theory of Metallic Conduction
The conduction of free electrons inside a conductor is best described by quantum mechanics. However, a classical model makes predictions close to the results of quantum mechanics. It is called the theory of metallic conduction.
In this theory, Newton's second law of motion is used to determine the acceleration of an electron in the presence of an applied electric field. Then, its velocity is expressed via this acceleration.
An electron moves through the crystal, containing positive ions,...
In this theory, Newton's second law of motion is used to determine the acceleration of an electron in the presence of an applied electric field. Then, its velocity is expressed via this acceleration.
An electron moves through the crystal, containing positive ions,...
Solid–Solid Solutions
The temperature-composition phase diagram of two solids, A and B, which are immiscible in the solid phase but form miscible liquids, shows that when the temperature is low, these two exist as separate, pure solids (A and B). As the temperature increases, they transition into a single-phase liquid solution where A and B coexist. Moving from point a1 to a2 in the phase diagram, the composition changes such that solid B begins to separate from the solution, enriching the remaining liquid with A.


