低压有机场效应晶体管与一个2-tridecyl[1]benzothieno[3,2-b][1]benzothiophene半导体层
Atefeh Y Amin1, Artoem Khassanov, Knud Reuter
1Organic Materials & Devices, Institute of Polymer Materials, Department of Materials Science, University of Erlangen-Nürnberg, Martensstraße 7, 91058 Erlangen, Germany.
Journal of the American Chemical Society
|September 26, 2012
概括
研究人员通过在C(13) -BTBT分子中创建非对称的替代模式来提高有机薄膜晶体管的性能. 这导致了高孔流动性和稳定的运行,为先进的电子设备铺平了道路.
科学领域:
- 有机电子学有机电子学
- 材料科学是一种材料科学.
- 半导体物理 半导体物理
背景情况:
- 有机薄膜晶体管 (OTFT) 对于灵活的电子产品至关重要.
- 提高电荷传输特性是提高OTFT性能的关键.
- 分子设计显著影响半导体的行为.
研究的目的:
- 通过非对称的n-基替代合成和研究2-tridecyl[1]benzothieno[3,2-b][1]benzothiophene (C(13) -BTBT).
- 为了提高有机半导体的电荷传输特性.
- 评估由此产生的OTFT设备的性能和稳定性.
主要方法:
- 不对称的n-基替代合成C(13) -BTBT.
- 有机薄膜晶体管的制造.
- 电气特性,以确定电荷载体的移动性.
- 进行X射线反射度测量以分析分子包装.
主要成果:
- 在低压设备中,可实现高孔流动度 (高达17.2厘米/V·s).
- 在通道界面观察到密集的C(13) -BTBT层,与高流动性相关.
- 显示出有希望的设备稳定性,在环境空气中连续运行数小时.
结论:
- 在C(13) -BTBT中的不对称替代有效地改善了OTFT中的收费运输.
- 受替模式影响的分子包装对于高性能至关重要.
- 这些发现表明C(13)-BTBT是稳定,高性能有机电子产品的一个有希望的材料.
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