对单壁碳纳米管具有各种替代物的功能化程度的分析
Yutaka Maeda1, Kazuma Saito, Norihisa Akamatsu
1Department of Chemistry, Tokyo Gakugei University, Tokyo 184-8501, Japan.
Journal of the American Chemical Society
|October 13, 2012
概括
功能化单壁碳纳米管 (SWNTs) 提高了可溶性. 控制替代剂添加是保持电子性质的关键,基团的体积使得功能控制精确.
科学领域:
- 材料科学 材料科学 材料科学
- 纳米技术 纳米技术
- 有机化学 有机化学
背景情况:
- 功能化单壁碳纳米管 (SWNTs) 提高了溶解度,并修改了性能.
- 过度功能化可能会降低SWNT的内在电子特性.
- 针对定制应用程序,对功能化程度和类型的精确控制至关重要.
研究的目的:
- 合成和表征侧墙功能化的SWNT,具有受控的替代度.
- 调查替代剂体积对功能化过程的影响.
- 探索SWNTs降解性化和化中的替代效应.
主要方法:
- 使用基和基化物合成功能化SWNT的一合成.
- 通过吸收光谱,拉曼光谱和热重力测量分析 (TGA) 进行表征.
- 使用综合光谱和TGA数据分析替代剂比率.
主要成果:
- 开发了一种方法来控制SWNT侧墙上的功能化程度.
- 证明了和酸中的基群的体积影响了功能化.
- 量化了功能化SWNT上的不同替代剂的比率.
- 在还原性化和化中研究的替代效应.
结论:
- 在SWNT上的功能化程度可以通过操纵基替代剂的硬质体积来有效控制.
- 这种控制允许调SWNT属性,同时最大限度地降低电子特征的退化.
- 该研究提供了对高级应用程序精确功能化的SWNTs的合成和表征的见解.
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