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Updated: May 16, 2026

Accessing Valuable Ligand Supports for Transition Metals: A Modified, Intermediate Scale Preparation of 1,2,3,4,5-Pentamethylcyclopentadiene
09:45

Accessing Valuable Ligand Supports for Transition Metals: A Modified, Intermediate Scale Preparation of 1,2,3,4,5-Pentamethylcyclopentadiene

Published on: March 20, 2017

1,1-非替代环坦的C ((sp3) -C ((sp3) 和C ((sp3) -H键的激活

Chisato Mukai1, Yuu Ohta, Yuki Oura

  • 1Division of Pharmaceutical Sciences, Graduate School of Medical Sciences, Kanazawa University, Kakuma-machi, Kanazawa 920-1192, Japan. mukai@p.kanazawa-u.ac.jp

Journal of the American Chemical Society
|November 14, 2012
PubMed
概括

这项研究表明,在未被激活的环白中,使用催化剂,出现了前所未有的C(sp(3)) -C(sp(3)) 键裂解. 通过新的循环添加反应合成了新的双环和螺旋环化合物.

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