电静电荷聚合物的接触去电
Siowling Soh1, Sen Wai Kwok, Helena Liu
1Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, Massachusetts 02138, United States.
Journal of the American Chemical Society
|November 17, 2012
概括
接触脱电是一种新发现的过程,在接触时同样带电的聚合物会在接触时放电. 这种向大气气体分子的快速电荷转移是由于接触点的介电分解强度超过而发生的.
科学领域:
- 材料科学 材料科学 材料科学
- 部落电力是部落的电力.
- 聚合物物理 聚合物物理
背景情况:
- 聚合物的接触电气化尚未完全理解,可能涉及多个电荷运动机制.
- 在这项研究中,研究了一种名为"接触脱电"的新型放电机制.
研究的目的:
- 描述和验证充电聚合物中的接触脱电机制.
- 为了研究这种排放过程在不同类型的聚合物和大气条件的普遍性.
主要方法:
- 实验性地将聚合物珠和平板 (聚胺6/6,聚氧甲,聚四乙烯,聚胺-胺) 充电到类似的极性.
- 在同样带电的聚合物样本之间接触时观察放电.
- 使用法拉第杯分析电荷转移到电离的大气气体分子.
主要成果:
- 带有正负电荷的聚合物 (尼龙,德林,特,托隆) 在接触时迅速放电.
- 不管接触的聚合物是相同的还是不同的材料,都会发生排放.
- 检测到电荷转移到电离的大气气体分子,支持拟议的机制.
结论:
- 接触脱电是一种对具有相同电荷的聚合物的一般机制,涉及由于接触时电场增加而导致大气气体的电离.
- 这一过程迅速释放聚合物,并且似乎独立于聚合物类型和大气成分.
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